A General Way,From L-Ascorbic And D-Isoascorbic Acids,To Homochiral α-Hydroxy, α,β-Dihydroxy And α,β-Epoxy-Aldehydes,Useful Building Blocks For The Synthesis Of Linear Oxygenated Fatty Acids Metabolites |
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| Authors: | Christine Gravier-Pelletier Jacques Dumas Yves Le Merrer Jean-Claude Depezay |
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| Institution: | Université René Descartes, Laboratoire de Chimie et Biochimie Pharmacologiques et Toxicologiques (URA 400 CNRS), 45 rue des Saints Pères, 75270 Paris Cedex 06, France |
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| Abstract: | AbstractEnantiomerically pure α-hydroxy, α,β-dihydroxy and α,β-epoxyaldehydes, useful building blocks for the synthesis of acyclic oxygenated fatty acids metabolites, were synthetized via epoxybutanediol acetonide starting from the commercially available L-ascorbic and D-isoascorbic acids. |
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