Solid-phase parallel synthesis of phosphite ligands |
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| Authors: | Swennenhuis Bert H G Chen Ruifang van Leeuwen Piet W N M de Vries Johannes G Kamer Paul C J |
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| Institution: | Van 't Hoff Institute of Molecular Sciences, University of Amsterdam, The Netherlands. |
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| Abstract: | Various routes for the synthesis of polymer-bound phosphites and phosphoramidites have been investigated. In the presence of a suitable activator the supported phosphoramidites react cleanly with alcohols to give the corresponding monodentate phosphite ligands in solution. We have applied this novel solid-phase route in the parallel synthesis of several monodentate chiral and achiral phosphite ligands. |
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