Recyclable polyurea-microencapsulated Pd(0) nanoparticles: an efficient catalyst for hydrogenolysis of epoxides |
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| Authors: | Ley Steven V Mitchell Claire Pears David Ramarao Chandrashekar Yu Jin-Quan Zhou Wuzong |
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| Institution: | Department of Chemistry, Cambridge University, Cambridge CB2 1EW, United Kingdom. |
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| Abstract: | reaction: see text] Pd nanoparticles (approximately 2 nm in size) microencapsulated in polyurea is an efficient and recyclable catalyst for reductive ring-opening hydrogenolysis of epoxides, using either HCOOH/Et(3)N or H(2) as a hydrogen donor. |
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