Unexpected remarkable stability of primary ozonides derived from alkenyl stannanes. One-pot synthesis of 1,2-diols from alkynes |
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| Authors: | Gómez Ana M Company María D Valverde Serafín López J Cristóbal |
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| Institution: | Instituto de Química Orgánica General (CSIC), Juan de la Cierva 3, 28006 Madrid, Spain. anago@iqog.csic.es |
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| Abstract: | Primary ozonides derived from alkenyl stannanes display an unusual stability and can be transformed into 1,2-diols by treatment with dimethyl sulfide and borane-methyl sulfide complex. This observation has been incorporated into the development of a novel one-pot strategy for the conversion of alkynes into 1,2-diols. |
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