Magnetism of [Ni(dmit)2] salts with [meso- and (1S, 2S)-diphenyl-1,2-ethanediammonium]([18]crown-6)2 supramolecular cations |
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Authors: | Akutagawa Tomoyuki Matsuura Kazumasa Hashimoto Asako Nakamura Takayoshi |
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Institution: | Research Institute for Electronic Science, Hokkaido University, N12W6 Sapporo, 060-0812, Japan. takuta@imd.es.hokudai.ac.jp |
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Abstract: | Meso- and (1S, 2S)-diphenyl-1,2-ethanediammonium (DPEDA2+) complexed with 18]crown-6 were introduced into Ni(dmit)2]-based magnetic salts as countercations. The configurational difference of DPEDA2+ modulated the crystal structure and magnetic behavior of the salts. A two-dimensional (2D) Heisenberg antiferromagnetic square lattice was observed in (meso-diphenyl-1,2-ethane diammonium2+)(18]crown-6)2Ni(dmit)2](-)2, which was the first example of a 2D magnetic lattice in Ni(dmit)2]- salts. |
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