Tetrahedral-shaped anions as a template in the synthesis of high-nuclearity silver(I) dithiophosphate clusters |
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| Authors: | Liao Jian-Hong Chang How-Wei You Hong-Chih Fang Ching-Shiang Liu C W |
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| Institution: | Department of Chemistry, National Dong Hwa University, Hualien, Taiwan 97401, Republic of China. |
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| Abstract: | Novel Ag(32) clusters, Ag(16)(EO(4)){S(2)P(OEt)(2)}(12)](2) (PF(6))(4) (E = S, 1; Se, 2) and Ag(16)(MO(4)){S(2)P(OEt)(2)}(12)](2)(PF(6))(4) (M = Cr, 3; Mo, 4), were prepared in situ from the addition of a tetrahedral-shaped anion as a template to the pentanuclear extended chain Ag(5){S(2)P(OEt)(2)}(4)](n)(PF(6))(n). |
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