Simultaneous first-derivative spectrophotometric determination of iron(III) and molybdenum(VI) in cobalt-chromium and nickel-chromium alloys |
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Authors: | Youssef El-Sayed A Khalil M M |
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Institution: | Department of Chemistry, Faculty of Science, Al-Azhar University, Assiut, Egypt. |
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Abstract: | A method is proposed for the simultaneous determination of iron(III) and molybdenum(VI) by first-derivative spectrophotometry based on the absorption spectra of their complexes with morin in the presence of a cationic surfactant. The zero-crossing measurement technique is found sutiable for the direct measurement of the first-derivative value at the specified wavelengths. Iron(III) (0.9-1.5 mug ml(-1)) and molybdenum(VI) (0.3-4.2 mug ml(-1)) in different ratios have been determined simultaneously. A critical evaluation of the proposed method is performed by statistical analysis of the experimental data. The method was applied to determine iron and molybdenum in different alloys. |
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