| 三唑-芳香多羧酸类混配金属配合物的结构与磁性能研究 |
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| 引用本文： | 刘忠义,刘婧,杨娜,杨恩翠,赵小军.三唑-芳香多羧酸类混配金属配合物的结构与磁性能研究[J].中国科学:化学,2013(10):1251-1261. |
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| 作者姓名： | 刘忠义 刘婧 杨娜 杨恩翠 赵小军 |
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| 作者单位： | 无机-有机杂化功能材料化学省部共建教育部重点实验室；天津市功能分子结构与性能重点实验室；天津师范大学化学学院,天津300387 |
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| 摘 要： | 以三唑为主配体的过渡金属配合物以其结构多样性及在磁性、吸附等功能材料中的潜在应用而成为众多科研工作者的研究热点内容之一．本文从三唑一芳香多羧酸混配配合物的合成以及芳香酸对配合物中金属一三唑次级结构的调节角度，总结了近年来报道的该类混配金属配合物的结构多样性．在此基础上，初步关联了该类混合配体顺磁金属配合物的磁一构关系．
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| 关 键 词： | 结构多样性 磁性能 三唑-多羧基 金属配合物 |
Structures and magnetic properties of mixed triazolyl-aromatic polycarboxylate-based metal complexes |
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| LIU ZhongYi,LIU Jing,YANG Na,YANG EnCui,ZHAO XiaoJun.Structures and magnetic properties of mixed triazolyl-aromatic polycarboxylate-based metal complexes[J].Scientia Sinica Chimica,2013(10):1251-1261. |
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| Authors: | LIU ZhongYi LIU Jing YANG Na YANG EnCui ZHAO XiaoJun |
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| Institution: | Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education; Tianjin Key Laboratory of Structure and Performance for Functional Molecules; College of Chemistry, Tianjin Normal University, Tianjin 300387, China |
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| Abstract: | Metal-triazolate complexes have recently received intense interest due to their various structures and promising applications in adsorption and magnetism. From the viewpoints of the synthesis of the triazolyl-aromatic polycarboxylate-based metal complexes and the effect of aromatic polycarboxylate coligand on the metal-triazolate subunits, in the present paper, the structural diversities as well as the relevant magnetic properties of the reaction system were summarized based on the available crystal structures and magnetic data reported within recent years. |
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| Keywords: | structural diversity magnetic property triazolyl-polycarboxylate metal complex |
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