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Different self-assembly behaviors of mono-modified β-cyclodextrin substituted by benzoic acid derivatives
基金项目:supported by the National Natural Science Foundation of China(20704031);;Tianjin Natural Science Fund(09JCYBJC06300);;Science Fund of Tianjin Education Committee(20060515)
摘    要:The mono-modified β-cyclodextrin derivative,6-O-(4-aminobenzoyl)-β-cyclodextrin(1) ,was synthesized and characterized. We compared its self-assembling behavior with structurally related β-cyclodextrin derivative,6-O-(4-hydroxybenzoyl)-βcyclodextrin(2) ,in aqueous solution and in the solid state using NMR spectroscopy and single crystal X-ray structure analysis. The two complexes displayed different self-assembling behaviors.Complex 1 formed a head-to-tail helical columnar superstructure in which the substit...

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