| 手性salen(Mn)催化烯烃不对称环氧化反应的研究进展 |
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| 引用本文： | 罗云飞,邹晓川,傅相锴,贾紫永,黄雪梅.手性salen(Mn)催化烯烃不对称环氧化反应的研究进展[J].中国科学:化学,2011(3):433-450. |
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| 作者姓名： | 罗云飞 邹晓川 傅相锴 贾紫永 黄雪梅 |
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| 作者单位： | 重庆市应用化学重点实验室三峡库区生态环境教育部重点实验室西南大学化学化工学院应用化学研究所;重庆教育学院生物与化学工程系; |
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| 基金项目： | 国家科技部科技中小型企业技术创新基金资助项目(09C26215112399); 国家人力资源和社会保障部留学人员回国创业启动支持计划项目(人社厅发2009(143号))基金资助 |
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| 摘 要： | 烯烃的不对称环氧化物通过选择性开环或者官能团的转化,可以生成一系列有价值的手性化合物,被广泛用作医药、农药、香料等精细化学品的合成中间体.手性Mn(salen)金属配合物被证明是烯烃不对称环氧化最有效的催化剂之一.本文综述了近年来均相手性Mn(salen)催化剂、有机聚合物固载的手性Mn(salen)、无机载体固载手性...
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| 关 键 词： | 手性Mn(salen)催化剂 有机聚合物载体 无机载体 有机聚苯乙烯-无机磷酸 锆杂化载体 |
The advance in asymmetric epoxidation of olefins catalyzed by chiral Mn(salen) |
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| LUO YunFei,ZOU XiaoChuan,FU XiangKai,JIA ZiYong & HUANG XueMei College of Chemistry , Chemical Engineering,Research Institute of Applied Chemistry,Southwest University,The Key Laboratory of Applied Chemistry of Chongqing Municipality,The Key Laboratory of Eco-environments in Three Gorges Reservoir Region ,Chongqing ,China.The advance in asymmetric epoxidation of olefins catalyzed by chiral Mn(salen)[J].Scientia Sinica Chimica,2011(3):433-450. |
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| Authors: | LUO YunFei ZOU XiaoChuan FU XiangKai JIA ZiYong & HUANG XueMei College of Chemistry Chemical Engineering Research Institute of Applied Chemistry Southwest University The Key Laboratory of Applied Chemistry of Chongqing Municipality The Key Laboratory of Eco-environments in Three Gorges Reservoir Region Chongqing China |
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| Institution: | LUO YunFei1,ZOU XiaoChuan1,2,FU XiangKai1,JIA ZiYong1 & HUANG XueMei1 1 College of Chemistry and Chemical Engineering,Research Institute of Applied Chemistry,Southwest University,The Key Laboratory of Applied Chemistry of Chongqing Municipality,The Key Laboratory of Eco-environments in Three Gorges Reservoir Region (Ministry of Education),Chongqing 400715,China 2 Department of Biological & Chemical Engineering,Chongqing Education College,Chongqing 400067,China |
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| Abstract: | The chiral Mn （Ⅲ） salen complexes have proven to be the most effective catalyst for asymmetric epoxidation of unfunctionalized olefins, which are highly significant in the pharmaceutical, agrochemical and spice fields to synthesize chiral building blocks that could be transformed into other useful chiral compounds through regioselective ring-opening reactions or by the selective transformation of functional groups. This paper reviews the homogeneous chiral Mn （salen） catalyst and the heterogeneous chiral Mn （salen） catalysts which immobilized onto organic polymer, inorganic support and organic polymer-inorganic hybrid materials catalyzed enantioselectivity epoxidation reactions of unfunctional olefins |
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| Keywords: | chiral Mn （Ⅲ） salen catalyst organic polymer support inorganic support organic polystyrene-inorganic zirconium phosphate hybrid support |
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