| 镓皂石的合成、交联及表征 |
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| 引用本文： | 姜廷顺,孙铁,沈剑平,郭金福,蒋大振,闵恩泽.镓皂石的合成、交联及表征[J].催化学报,1994,15(2):121-126. |
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| 作者姓名： | 姜廷顺 孙铁 沈剑平 郭金福 蒋大振 闵恩泽 |
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| 作者单位： | 吉林大学化学系，石油化工科学研究院，河南安阳师专 |
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| 摘 要： | 用水热法合成了镓皂石，并用Ａｌ１３齐聚物进行交联．经ＸＲＤ，ＩＲ，ＭＡＳＮＭＲ和元素分析表征，结果显示镓存在于粘土层四面体骨架中，交联剂引入量与层四面体中镓含量有关，层与柱键合可能发生在ＧａＯ４四面体上．
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| 关 键 词： | 镓，皂石，合成，交联，羟基铝齐聚物 |
SYNTHESIS, CROSS-LINKING AND CHARACTERIZATION OF Ga-SUBSTITUTED SAPONITE |
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| Jiang,Ting-shun,Sun,Tie,Shen,Jian-ping,Guo,Jin-fu, Jiang,Da-zhen.SYNTHESIS, CROSS-LINKING AND CHARACTERIZATION OF Ga-SUBSTITUTED SAPONITE[J].Chinese Journal of Catalysis,1994,15(2):121-126. |
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| Authors: | Jiang Ting-shun Sun Tie Shen Jian-ping Guo Jin-fu Jiang Da-zhen |
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| Abstract: | a-substituted saponites were synthesized in terms of hydrothermal method,and their cross-linking materials were prepared by hydroxyl aluminium oligomer.Above samples were characterized by means of XRD, IR, MASNMR and element analysis.The results indicate that gallium is present in the tetrahedral sheet framework of layered clay.The amount of cross-linking agent introduced is related to the amount of gallium in the tetrahedron. The binding of pillar with sheet maybe occurred on the GaO4 tetrahedroh. |
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| Keywords: | synthesis gallium saponite cross-linking hydroxyl aluminium oligomer |
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