| 含二茂铁和吡啶单元的手性席夫碱配体在钌催化的不对称氢转移反应中的应用 |
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| 引用本文： | 戴慧聪,胡向平,陈惠麟,白长敏,郑卓.含二茂铁和吡啶单元的手性席夫碱配体在钌催化的不对称氢转移反应中的应用[J].催化学报,2003,24(8):565-566. |
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| 作者姓名： | 戴慧聪 胡向平 陈惠麟 白长敏 郑卓 |
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| 作者单位： | Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China |
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| 基金项目： | 国家自然科学基金，29933050， |
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| 摘 要： | Chiral Schiff base complexes are very efficient for a wide range of reactions, including expoxidation1], epoxide ring opening2], Diels-Alder reaction3], aldol reaction4], etc. However, there are only few examples of P-N chelate Schiff bases being used as the chiral ligands in the asymmetric transfer hydrogenation of ketones. Recently, Gao et al5] reported a series of P,N,N,P Schiff base ligands that have relatively low enantioselectivity in the asymmetric transfer hydrogenation of ketones.
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| 关 键 词： | Schiff base chiral ligand ferrocene |
Chiral Schiff Base Ligands Containing Ferrocene and Pyridine Units for Ruthenium-Catalyzed Asymmetric Transfer Hydrogenation |
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| DAI Huicong,HU Xiangping,Chen Huilin,BAI Changmin,ZHENG Zhuo.Chiral Schiff Base Ligands Containing Ferrocene and Pyridine Units for Ruthenium-Catalyzed Asymmetric Transfer Hydrogenation[J].Chinese Journal of Catalysis,2003,24(8):565-566. |
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| Authors: | DAI Huicong HU Xiangping Chen Huilin BAI Changmin ZHENG Zhuo |
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| Abstract: | Chiral Schiff base complexes are very efficient for a wide range of reactions, including expoxidation1], epoxide ring opening2], Diels-Alder reaction3], aldol reaction4], etc. However, there are only few examples of P-N chelate Schiff bases being used as the chiral ligands in the asymmetric transfer hydrogenation of ketones. Recently, Gao et al5] reported a series of P,N,N,P Schiff base ligands that have relatively low enantioselectivity in the asymmetric transfer hydrogenation of ketones. |
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| Keywords: | pyridine ruthenium asymmetric transfer hydrogenation |
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