| 金催化剂上脂肪族硝基化合物与醛在氢气中选择还原耦合 |
| |
| 作者姓名： | Larisha Cisneros Pedro Serna Avelino Corma |
| |
| 作者单位： | 1. 瓦伦西亚理工大学-西班牙国家研究委员会，化学工程研究所，瓦伦西亚46022，西班牙;2. 埃克森美孚研究与工程有限公司企业战略研究，新泽西08801，美国 |
| |
| 基金项目： | Consolider-Ingenio 2010，Generalitat Valenciana，Severo Ochoa Program(SEV-2012-0267)，the CONACyT Program(3115621) |
| |
| 摘 要： | 采用TiO2上高度分散的金纳米粒子做催化剂，从脂肪族硝基化合物、醛和氢气可高选择性合成硝酮。与碳负载Pt催化剂相比，该催化体系上硝酮的选择性从50%增加到90%。其催化性能可有活性位结构、载体特性和反应条件精确调节。
|
| 关 键 词： | 金催化剂 硝基化合物 串联反应 加氢 硝酮 |
Selective reductive coupling of nitro aliphatic compounds with aldehydes in hydrogen using gold catalyst |
| |
| Larisha Cisneros,Pedro Serna,Avelino Corma.Selective reductive coupling of nitro aliphatic compounds with aldehydes in hydrogen using gold catalyst[J].Chinese Journal of Catalysis,2016(10):1756-1763. |
| |
| Authors: | Larisha Cisneros Pedro Serna Avelino Corma |
| |
| Abstract: | Nitrones were synthesized in good yields directly from nitro aliphatic compounds, aldehydes, and H2 using highly dispersed gold nanoparticles on titania. The high selectivity for nitrone synthesis contrasts with the platinum supported on carbon and corresponds to an increase from roughly 50%to 90%. The catalytic performance is tuned by precise control of the structure of the active sites, the characteristics of the support and reaction conditions. |
| |
| Keywords: | Gold catalyst Nitro compound Cascade-type reaction Hydrogenation Nitrone |
| 本文献已被 万方数据 等数据库收录！ |
