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| 苯磺酰胺参与下二价钌催化环丙乙炔扩环反应 | |
| 引用本文： | 陈雨叶,汪俊松,李兴伟,贾爱群.苯磺酰胺参与下二价钌催化环丙乙炔扩环反应[J].催化学报,2013,34(10):1816-1819. |
| 作者姓名： | 陈雨叶 汪俊松 李兴伟 贾爱群 |
| 作者单位： | a 南京理工大学环境与生物工程学院, 江苏南京210014; b 中国科学院大连化学物理研究所, 辽宁大连116023 |
| 基金项目： | the National Natural Science Foundation of China(31070312,31170131);the Jiangsu Qinglan Project;the Fundamental Research Funds for the Central Universities(30920130121013)~~ |
| 摘 要： | 将二价钌配合物用于催化环丙乙炔扩环生成四元环结构的反应,扩展了一系列环丙乙炔底物和磺酰胺底物,并得到了较高的产率. |
| 关 键 词： | 过渡金属 钌催化 扩环反应 苯磺酰胺 |
| 收稿时间： | 2013-08-04 |
Ru(Ⅱ)-catalyzed ring expansion of alkynylcyclopropanes in the presence of sulfonamides |
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| Yuye Chen;Junsong Wang;Xingwei Li;Aiqun Jia.Ru(Ⅱ)-catalyzed ring expansion of alkynylcyclopropanes in the presence of sulfonamides[J].Chinese Journal of Catalysis,2013,34(10):1816-1819. | |
| Authors: | Yuye Chen;Junsong Wang;Xingwei Li;Aiqun Jia |
| Institution: | a School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210014, Jiangsu, China; b Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China |
| Abstract: | Ru(II)-catalyzed ring expansion of alkynylcyclopropanes to alkylidenecyclobutanamines using a variety of cyclopropane and sulfonamide substrates was developed and shown to give moderate to excellent yields. |
| Keywords: | Transition metal Ruthenium Catalysis Ring expansion Sulfonamide |
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