| N,N-二甲基苄胺催化合成丙烯酸间苯二酚环氧酯的机理 |
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| 引用本文： | 高俊刚,王洪芬,袁翠红.N,N-二甲基苄胺催化合成丙烯酸间苯二酚环氧酯的机理[J].催化学报,1994,15(5):404-408. |
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| 作者姓名： | 高俊刚 王洪芬 袁翠红 |
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| 作者单位： | 河北大学化学系 |
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| 摘 要： | Ｎ，Ｎ－二甲基苄胺催化合成丙烯酸间苯二酚环氧酯的机理高俊刚，王洪芳，袁翠红（河北大学化学系，保定０７１００２）关键词丙烯酸间苯二酚环氧酯，Ｎ，Ｎ－二甲基苄胺，催化反应机理不饱和酸环氧酯是由不饱和核酸与环氧化合物进行环氧化反应形成的一种化合物，它在涂料...
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| 收稿时间： | 1994-10-25 |
STUDIES ON THE REACTION MECHANISM AND KINETICS OF m-PHENDIOL EPOXY ACRYLATE SYNTHESIS |
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| Gao,Jun-gang, Wang,Hong-fang and Yuan,Cul-hong.STUDIES ON THE REACTION MECHANISM AND KINETICS OF m-PHENDIOL EPOXY ACRYLATE SYNTHESIS[J].Chinese Journal of Catalysis,1994,15(5):404-408. |
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| Authors: | Gao Jun-gang Wang Hong-fang and Yuan Cul-hong |
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| Abstract: | he reaction mechanism and kinetics of m-phendiol epoxy acrylatesynthesis catalyzed by dimethylbenzylamine (DMBA) have been studied. In the reaction process, the complex of acrylic acid with catalystDMBA is first formed, then the reaction between epoxy group andacrylic acid is catalyzed by it. The order of the reaction is 1, 0 and 0. 72with respect to epoxy qroup, acrylic acid and DMBA, respectively. |
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| Keywords: | m-phendiol epoxy acrylate N N-dimethyl benzylamine catalytic reaction mechanism |
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