| La2O3助剂对Au/TiO2催化肉桂醛选择性加氢性能的影响 |
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| 引用本文： | 刘迎新,孟令富,魏作君,时洪涛.La2O3助剂对Au/TiO2催化肉桂醛选择性加氢性能的影响[J].催化学报,2011,32(7):1269-1274. |
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| 作者姓名： | 刘迎新 孟令富 魏作君 时洪涛 |
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| 作者单位： | 1. 浙江工业大学催化加氢研发基地,浙江杭州,310032
2. 浙江大学化学工程与生物工程学系,浙江杭州,310027 |
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| 基金项目： | 浙江省自然科学基金(Y4100671)~~ |
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| 摘 要： | 以溶胶-凝胶法制得的TiO2和La2O3-TiO2为载体,采用沉积-沉淀法制备了一系列Au催化剂,用于肉桂醛选择性加氢反应,并运用N2吸附-脱附、X射线衍射、高分辨率透射电镜、程序升温还原和X射线光电子能谱等方法对催化剂进行了表征,系统考察了La2O3含量对Au/TiO2催化剂物化性质和催化性能的影响.结果表明,适量L...
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| 关 键 词： | 金 负载型催化剂 氧化镧 助剂 肉桂醛 选择性加氢 肉桂醇 |
Effect of La_2O_3 Promoter on the Performance of Au/TiO_2 Catalyst for Selective Hydrogenation of Cinnamaldehyde |
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| LIU Yingxin,MENG Lingfu,WEI Zuojun,SHI Hongtao.Effect of La_2O_3 Promoter on the Performance of Au/TiO_2 Catalyst for Selective Hydrogenation of Cinnamaldehyde[J].Chinese Journal of Catalysis,2011,32(7):1269-1274. |
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| Authors: | LIU Yingxin MENG Lingfu WEI Zuojun SHI Hongtao |
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| Institution: | LIU Yingxin1,MENG Lingfu1,WEI Zuojun2,SHI Hongtao1 1Research and Development Base of Catalytic Hydrogenation,Zhejiang University of Technology,Hangzhou 310032,Zhejiang,China 2Department of Chemical and Biological Engineering,Zhejiang University,Hangzhou 310027,China |
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| Abstract: | Using TiO2 and La2O3-doped TiO2 as supports,which were prepared by the sol-gel method,a series of Au catalysts were prepared by the deposition-precipitation method. Their catalytic performance for selective hydrogenation of cinnamaldehyde was tested and their physical and chemical properties were investigated by the techniques of N2 adsorption-desorption,X-ray diffraction,high-resolution trans-mission electron microscopy,temperature-programmed reduction,and X-ray photoelectron spectroscopy. The results show... |
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| Keywords: | gold supported catalyst lanthanum oxide promoter cinnamaldehyde selective hydrogenation cinnamyl alcohol |
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