| 阳离子表面活性剂存在下水/有机两相体系中双环戊二烯氢甲酰化 |
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| 引用本文： | 皮晓栋,周娅芬,周丽梅,袁茂林,李瑞祥,付海燕,陈华.阳离子表面活性剂存在下水/有机两相体系中双环戊二烯氢甲酰化[J].催化学报,2011,32(4):566-571. |
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| 作者姓名： | 皮晓栋 周娅芬 周丽梅 袁茂林 李瑞祥 付海燕 陈华 |
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| 作者单位： | 四川大学化学学院绿色化学与技术教育部重点实验室;华西师范大学化学与化工学院; |
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| 基金项目： | supported by the National Natural Science Foundation of China(29792074); the National Basic Research Program of China(973 Program,G2000048008)~~ |
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| 摘 要： | 研究了在阳离子表面活性剂存在下水/有机两相中水溶性铑配合物RhCI(CO)(TPPTS)2(TPPTS:P(m-C6H4SO3Na)3)催化双环戊二烯氢甲酰化反应,考察了反应温度、催化剂浓度、不同水溶性膦配体TPPTS和TPPDS(C5H5P(m-C6H4SO3Na)2),以及表面活性剂结构对催化反应的影响.结果表明,...
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| 关 键 词： | 水/有机两相体系 双环戊二烯 氢甲酰化 铑 表面活性剂 |
Dicyclopentadiene Hydroformylation in an Aqueous/Organic Two Phase System in the Presence of a Cationic Surfactant |
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| PI Xiaodong,ZHOU Yafen,ZHOU Limei,YUAN Maolin,LI Ruixiang,FU Haiyan,CHEN Hua.Dicyclopentadiene Hydroformylation in an Aqueous/Organic Two Phase System in the Presence of a Cationic Surfactant[J].Chinese Journal of Catalysis,2011,32(4):566-571. |
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| Authors: | PI Xiaodong ZHOU Yafen ZHOU Limei YUAN Maolin LI Ruixiang FU Haiyan CHEN Hua |
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| Institution: | PI Xiaodong1,ZHOU Yafen1,2,ZHOU Limei1,YUAN Maolin1,LI Ruixiang1,FU Haiyan1,b,CHEN Hua1,a 1Key Laboratory of Green Chemistry and Technology of Ministry of Education,Department of Chemistry,Sichuan University,Chengdu 610064,Sichuan,China 2College of Chemistry and Chemical Engineering,China West Normal University,Nanchong 637002,China |
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| Abstract: | Dicyclopentadiene (DCPD) hydroformylation catalyzed by the water soluble rhodium complex RhCl(CO)(TPPTS)2 (TPPTS:P(m-C6H4SO3Na)3) was studied in an aqueous/organic two phase system containing a cationic surfactant.The effects of various reaction parameters such as reaction temperature,catalyst concentration,water soluble phosphine TPPTS or TPPDS (C6H5P(m-C6H4SO3Na)2),and surfactant structure were examined.The catalytic activity was better with the ligand TPPTS than with TPPDS.The reaction was accelerated by... |
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| Keywords: | aqueous/organic two phase system dicyclopentadiene hydroformylation rhodium surfactant |
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