| 高载量、高活性Ni/Al2O3催化剂的制备及其芳环加氢催化反应 |
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| 引用本文： | 胡胜华,薛明伟,陈慧,孙寅璐,沈俭一.高载量、高活性Ni/Al2O3催化剂的制备及其芳环加氢催化反应[J].催化学报,2011,32(6):917-925. |
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| 作者姓名： | 胡胜华 薛明伟 陈慧 孙寅璐 沈俭一 |
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| 作者单位： | 南京大学化学化工学院介观化学教育部重点实验室; |
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| 基金项目： | supported by the National Basic Research Program of China(973 Program,2005CB221400); the National Natural Science Foundation of China(20673055 and 21073089); Industrial Supporting Project of Jiangsu Province(BE2009145)~~ |
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| 摘 要： | 使用共沉淀法制备了担载量很高的Ni/Al2O3催化剂,通过正丁醇干燥处理,提高了催化剂的表面积和担载镍的分散度.实验发现,镍的担载量和干燥过程刘催化剂的表面积、孔结构及金属镍的还原度和分散度影响很大.经过正丁醇处理的80%Ni/Al2O3-B催化剂具有较高的表面积,而担载镍的还原度和分散度也显著提高,使得催化剂具有很高...
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| 关 键 词： | 镍 氧化铝 正丁醇干燥 活性金属表面积 微量吸附量热 甲苯加氢 苯酚加氢 |
Preparation of Highly Loaded and Active Ni/Al_2O_3 Catalysts for the Hydrogenation of Aromatic Rings |
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| HU Shenghua,XUE Mingwei,CHEN Hui,SUN Yinlu,SHEN Jianyi.Preparation of Highly Loaded and Active Ni/Al_2O_3 Catalysts for the Hydrogenation of Aromatic Rings[J].Chinese Journal of Catalysis,2011,32(6):917-925. |
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| Authors: | HU Shenghua XUE Mingwei CHEN Hui SUN Yinlu SHEN Jianyi |
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| Institution: | HU Shenghua,XUE Mingwei,CHEN Hui,SUN Yinlu,SHEN Jianyi Laboratory of Mesoscopic Chemistry,School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210093,Jiangsu,China |
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| Abstract: | Highly loaded and dispersed Ni/Al2O3-B catalysts were prepared by the co-precipitation method with an n-butanol drying process.The loading of nickel and drying process were found to be the two key factors in determining the surface area and pore structures of catalysts as well as the reducibility and dispersion of supported nickel.The 80%Ni/Al2O3-B treated with n-butanol during the drying process exhibited the high surface area and high reducibility and dispersion of supported nickel,leading to the high act... |
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| Keywords: | Ni/Al2O3 catalyst drying with n-butanol active metal surface area microcalorimetric adsorption hydrogenation of toluene hydrogenation of phenol |
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