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活性艳红X-3B水溶液的光化学与光催化协同脱色反应
引用本文:毛立群,杨建军,郭泉辉,李庆霖,张治军.活性艳红X-3B水溶液的光化学与光催化协同脱色反应[J].催化学报,2001,22(2):181-184.
作者姓名:毛立群  杨建军  郭泉辉  李庆霖  张治军
作者单位:河南大学润滑与功能材料重点实验室, 开封 475001
摘    要: 对影响活性艳红X-3B水溶液光化学与光催化协同脱色反应的各种条件(如溶液的pH值,紫外光照强度,空气流量,催化剂用量及溶液的初始浓度等)进行了考察.结果表明,降解率随着紫外光照强度的增强而加快,随着X-3B初始浓度的增大而减慢;催化剂最佳用量为4g/L,空气最佳流量为4.3L/h.在X-3B水溶液的光催化脱色过程中,存在有光解反应,但它远不如光催化反应重要.因此,活性艳红X-3B水溶液的降解是光化学与光催化的协同脱色反应.

关 键 词:光催化  光解  脱色反应  活性艳红X-3B
文章编号:0253-9837(2001)02-0181-04
收稿时间:2001-04-25

Studies on Photochemical and Photocatalytic Synergistic Decoloration of Brilliant Red X-3B Solution
MAO Liqun,YANG Jianjun,GUO Quanhui,LI Qinglin ,ZHANG Zhijun.Studies on Photochemical and Photocatalytic Synergistic Decoloration of Brilliant Red X-3B Solution[J].Chinese Journal of Catalysis,2001,22(2):181-184.
Authors:MAO Liqun  YANG Jianjun  GUO Quanhui  LI Qinglin  ZHANG Zhijun
Institution:MAO Liqun,YANG Jianjun,GUO Quanhui,LI Qinglin *,ZHANG Zhijun
Abstract:The photocatalytic and photolytic decoloration reactions ofaqueous brilliant red X-3B solution were studied. Th e experimental results showed that the reaction rate was increased with incre asing UV light intensity, and decreased with increasing the initial X-3B concentration . An optimized content of the catalyst in solution was foun d at 4 g/L and an optimized air flow was found at 4.3 L/h. Particularly, the photolysis was found during the photocatalytic dec olor ation of aqueous X-3B solution, though its effect on the reaction was far infer ior t o that of photocatalytic decoloration, so the decoloration of aqueous brilliant red X-3B sol ution is a concerted reaction of photolytic and photocatalytic decoloration in t he range of pH=3~11.
Keywords:photocatalysis  photolysis  decoloration  brilliant red X  3B
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