| 钯催化烯丙基磺酰胺的分子内胺氟化反应 |
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| 引用本文： | 程家顺,陈品红,刘国生.钯催化烯丙基磺酰胺的分子内胺氟化反应[J].催化学报,2015,36(1):40-47. |
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| 作者姓名： | 程家顺 陈品红 刘国生 |
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| 作者单位： | 中国科学院上海有机化学研究所金属有机国家重点实验室,上海,200032 |
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| 基金项目： | the National Basic Research Program of China，the National Natural Science Foundation of China，the Science and Technology Commission of Shanghai Municipality，the CAS/SAFEA International Partnership Program for Creative Research Teams.基金来源:国家重点基础研究发展计划，国家自然科学基金，上海市科学技术委员会，中国科学院、国家外国专家局创新团队国际合作伙伴计划 |
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| 摘 要： | 报道了钯催化的非活性烯烃的胺氟化反应,在酸性添加剂HOAc的作用下,反应以较好的收率和区域选择性地得到6-endo环合产物,实现了氟代的环状磺胺类产物的有效合成.
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| 关 键 词： | 钯催化 胺氟化 烯烃 氟代1 3-二胺 6-endo环合 |
| 收稿时间： | 2014-05-19 |
Pd-catalyzed intramolecular aminofluorination of allylic sulfamides |
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| Jiashun Cheng
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Pinhong Chen
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Guosheng Liu.Pd-catalyzed intramolecular aminofluorination of allylic sulfamides[J].Chinese Journal of Catalysis,2015,36(1):40-47. |
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| Authors: | Jiashun Cheng Pinhong Chen Guosheng Liu |
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| Institution: | State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China |
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| Abstract: | A facile Pd-catalyzed intramolecular aminofluorination reaction of allylic sulfamides was developed that can be used to prepare fluorinated 1,3-diamine derivatives. Acetic acid was essential for regulation to give the major 6-endo cyclization products. |
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| Keywords: | Palladium-catalyzed Aminofluorination Alkene Fluorinated 1 3-diamine 6-Endo cyclization |
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