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| 乙酸功能化离子液体作为高效、可回收的催化剂用于2-萘酚与芳醛缩合反应(英文) | |
| 作者姓名： | Ahmad Reza Moosavi-Zare Mohammad Ali Zolfigol Omid Khaledian Vahid Khakyzadeh |
| 作者单位： | a Department of Chemistry, University of Sayyed Jamaleddin Asadabadi, Asadabad, 6541835583, Iran; b Faculty of Chemistry, Bu Ali Sina University, Hamedan, 6517838683, Iran |
| 基金项目： | supported by Bu-Ali Sina University and University of Sayyed Jamaleddin Asadabadi, Asadabad |
| 摘 要： | An efficient solvent‐free protocol for the synthesis of 14‐aryl‐14H‐dibenzoa,j]xanthenes from the condensation of 2‐naphthol with arylaldehydes, using acetic acid functionalized imidazolium salts (1‐carboxymethyl‐3‐methylimidazolium bromide (cmmim]Br) and 1‐carboxymethy1‐3-me-thylimidazolium tetrafluoroborate(cmmim]BF4) as reusable catalysts, has been developed. The turn over frequency on the catalysts is several times higher than the other previously reported catalysts. Also, thermal gravimetric analysis and powder X‐ray diffraction pattern of the catalysts have been studied. |
| 关 键 词： | ‐Aryl‐H‐dibenzo[a j]xanthene Acetic acid functionalized ionic liquid ‐Naphthol Aldehyde Catalyst Solvent‐free |
| 收稿时间： | 2013-12-03 |
Condensation of 2-naphtol with arylaldehydes using acetic acid functionalized ionic liquids as highly efficient and reusable catalysts |
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| Ahmad Reza Moosavi-Zare,Mohammad Ali Zolfigol,Omid Khaledian,Vahid Khakyzadeh.Condensation of 2-naphtol with arylaldehydes using acetic acid functionalized ionic liquids as highly efficient and reusable catalysts[J].Chinese Journal of Catalysis,2014,35(4):573-578. | |
| Authors: | Ahmad Reza Moosavi-Zare Mohammad Ali Zolfigol Omid Khaledian Vahid Khakyzadeh |
| Institution: | a Department of Chemistry, University of Sayyed Jamaleddin Asadabadi, Asadabad, 6541835583, Iran; b Faculty of Chemistry, Bu Ali Sina University, Hamedan, 6517838683, Iran |
| Abstract: | An efficient solvent-free protocol for the synthesis of 14-aryl-14H-dibenzoa,j]xanthenes from the condensation of 2-naphthol with arylaldehydes, using acetic acid functionalized imidazolium salts (1-carboxymethyl-3-methylimidazolium bromide (cmmim]Br) and 1-carboxymethy1-3-methylimidazolium tetrafluoroborate (cmmim]BF4) as reusable catalysts, has been developed. The turn over frequency on the catalysts is several times higher than the other previously reported catalysts. Also, thermal gravimetric analysis and powder X-ray diffraction pattern of the catalysts have been studied. |
| Keywords: | 14-Aryl-14H-dibenzo[a j]xanthene Acetic acid functionalized ionic liquid 2-Naphthol Aldehyde Catalyst Solvent-free |
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