| 无溶剂条件下N-磺酸琥珀酰亚胺催化乙酰化反应(英文) |
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| 作者姓名： | Farhad SHIRINI Nader Ghaffari KHALIGH |
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| 作者单位： | Department of Chemistry, Faculty of Sciences, University of Guilan, Rasht, zip code 41335, Post box 1914, Iran |
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| 基金项目： | the University of Guilan Research Council for the partial support of this work |
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| 摘 要： | A small amount of succinimide-N-sulfonic acid efficiently catalyzed the acetylation of a variety alcohols, phenols, thiols, amines and aldehydes with acetic anhydride at room temperature under solvent free conditions. This catalyst has the advantages of excellent yields and short reaction times and the reaction can be carried out on a large scale, which makes it potentially useful for industrial applications.
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| 关 键 词： | Succinimde‐N‐sulfonic acid Protection Acetylation Chemoselective reaction Solvent‐free condition |
A succinimide-N-sulfonic acid catalyst for acetylation reactions in absence of a solvent |
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| Farhad SHIRINI,Nader Ghaffari KHALIGH.A succinimide-N-sulfonic acid catalyst for acetylation reactions in absence of a solvent[J].Chinese Journal of Catalysis,2013,34(4):695-703. |
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| Authors: | Farhad SHIRINI Nader Ghaffari KHALIGH |
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| Institution: | Department of Chemistry, Faculty of Sciences, University of Guilan, Rasht, zip code 41335, Post box 1914, Iran |
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| Abstract: | A small amount of succinimide-N-sulfonic acid efficiently catalyzed the acetylation of a variety alcohols, phenols, thiols, amines and aldehydes with acetic anhydride at room temperature under solvent free conditions. This catalyst has the advantages of excellent yields and short reaction times and the reaction can be carried out on a large scale, which makes it potentially useful for industrial applications. |
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| Keywords: | Succinimde-N-sulfonic acid Protection Acetylation Chemoselective reaction Solvent-free condition |
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