| 以原位形成的磷酸铝骨架为模板制备纳米孔炭(英文) |
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| 引用本文： | 张敏,朱万春,刘钢,张秀艳,祖艳红,张文祥,闫文付,贾明君.以原位形成的磷酸铝骨架为模板制备纳米孔炭(英文)[J].催化学报,2012(3):465-472. |
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| 作者姓名： | 张敏 朱万春 刘钢 张秀艳 祖艳红 张文祥 闫文付 贾明君 |
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| 作者单位： | 吉林大学化学学院理论化学计算国家重点实验室;吉林大学化学学院无机合成与制备国家重点实验室 |
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| 基金项目： | 吉林省科学与技术发展计划(201105009);高等学校博士点基金新教师项目(20090061120024);国家自然科学基金(21003059)~~ |
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| 摘 要： | 以不同有机物(邻苯二酚、间苯二酚、对苯二酚、乙二醇、环己胺)为辅助炭源,通过直接炭化含柠檬酸及磷酸铝的复合物制备了一系列纳米孔炭材料(NC),采用多种表征手段研究了辅助炭源对最终炭材料性质的影响.结果表明,NC材料的结构和表面官能团性质随辅助炭源的变化而改变,其中以间苯二酚、对苯二酚、环己胺为辅助炭源制备的炭材料在空气氧化苯甲醇反应中表现有较高的催化活性.
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| 关 键 词： | 纳米孔炭 磷酸铝 表面官能团 苯甲醇 空气氧化 |
Preparation of Nanoporous Carbon Using an Aluminophosphate Framework Template |
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| ZHANG Min,ZHU Wanchun,LIU Gang,a, ZHANG Xiuyan,ZU Yanhong,ZHANG Wenxiang,YAN Wenfu,JIA Mingjun.Preparation of Nanoporous Carbon Using an Aluminophosphate Framework Template[J].Chinese Journal of Catalysis,2012(3):465-472. |
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| Authors: | ZHANG Min ZHU Wanchun LIU Gang a ZHANG Xiuyan ZU Yanhong ZHANG Wenxiang YAN Wenfu JIA Mingjun |
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| Institution: | 1,b 1State Key Laboratory of Theoretical and Computational Chemistry, College of Chemistry, Jilin University, Changchun 130021, Jilin, China 2State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, Jilin, China |
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| Abstract: | Different organic compounds, o-dihydroxybenzene, m-dihydroxybenzene, p-dihydroxybenzene, glycol, and cyclohexylamine, were used as the extra carbon source for a series of nanoporous carbon (NC) materials prepared by directly carbonizing composites containing citric acid and aluminum phosphate. The effect of the extra carbon source was studied. The structure and surface functional groups on the NC material were different with different extra carbon sources. The NC materials prepared using m-dihydroxybenzene, p-dihydroxybenzene or cyclohexylamine have excellent catalytic activity for the aerobic oxidation of benzyl alcohol to benzaldehyde. |
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| Keywords: | nanoporous carbon aluminophosphate surface functional group benzyl alcohol aerobic oxidation |
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