| 负载脯氨酸及其衍生物催化的不对称C-C键形成反应研究进展 |
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| 引用本文： | 刘玉霞,杨柳,马志伟,王川川,陶京朝.负载脯氨酸及其衍生物催化的不对称C-C键形成反应研究进展[J].催化学报,2011(8):1295-1311. |
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| 作者姓名： | 刘玉霞 杨柳 马志伟 王川川 陶京朝 |
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| 作者单位： | 郑州大学化学系;河南工程学院材料与化学工程系 |
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| 基金项目： | 国家自然科学基金(20372059);河南工程学院博士基金(D09002)~~ |
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| 摘 要： | 近年来脯氨酸及其衍生物催化的不对称有机反应受到了广泛关注,将其负载于载体上使用也引起了人们的极大兴趣.负载方式大致分为3种:共价键负载,离子对结合或物理吸附等作用负载,以及在离子液体中的两相催化剂.本文对近年来出现的负载脯氨酸及其衍生物催化的不对称反应(Aldol反应、Michael加成反应)研究进展进行了综述.
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| 关 键 词： | 负载型催化剂 有机催化 L-脯氨酸 碳-碳键形成反应 |
Research Progress in Supported Proline and Proline Derivatives as Recyclable Organocatalysts for Asymmetric C—C Bond Formation Reactions |
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| LIU Yuxia,a, YANG Liu,MA Zhiwei,WANG Chuanchuan,TAO Jingchao.Research Progress in Supported Proline and Proline Derivatives as Recyclable Organocatalysts for Asymmetric C—C Bond Formation Reactions[J].Chinese Journal of Catalysis,2011(8):1295-1311. |
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| Authors: | LIU Yuxia a YANG Liu MA Zhiwei WANG Chuanchuan TAO Jingchao |
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| Institution: | 1,b 1Department of Chemistry, Zhengzhou University, Zhengzhou 450052, Henan, China 2Department of Material and Chemistry Engineering, Henan Institute of Engineering, Zhengzhou 450007, Henan, China |
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| Abstract: | In recent years, L-proline and L-proline derivatives were successfully used as organocatalysts in asymmetric reactions. There are three different general approaches for organocatalyst immobilization: covalently supported catalysts, non-covalently supported catalysts, and biphasic catalysts in ionic liquids. This review summarizes some immobilized organocatalysts, highlighting their application, recoverability, and reusability in Aldol and Michael addition reactions. |
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| Keywords: | supported catalyst organocatalysis L-proline carbon-carbon bong formation reaction |
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