| 硒催化硝基苯的还原羰基化生成苯氨基甲酸酯 |
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| 引用本文： | 杨瑛,陆世维.硒催化硝基苯的还原羰基化生成苯氨基甲酸酯[J].催化学报,1999,20(3):224-226. |
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| 作者姓名： | 杨瑛 陆世维 |
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| 作者单位： | 中国科学院大连化学物理研究所国家催化工程技术研究中心,大连,116023 |
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| 摘 要： | 详细考察了醇介质中硒催化的硝基苯还原羰基化生成苯氨基甲酸酯的反应，获得了一系列苯氨基甲酸酯产物。结果表明，硒粉催化活性高，反应产率和选择性良好，反应工艺简单。文中对反应提出了可能的机理。
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| 关 键 词： | 均相催化 Se羰基化 硝基苯 |
| 收稿时间： | 1999-06-25 |
SELENIUM-CATALYZED REDUCTIVE CARBONYLATION OF PhNO2 IN ALCOHOL MEDIA TO PHENYL CARBAMATES |
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| Yang Ying,Lu Shiwei.SELENIUM-CATALYZED REDUCTIVE CARBONYLATION OF PhNO2 IN ALCOHOL MEDIA TO PHENYL CARBAMATES[J].Chinese Journal of Catalysis,1999,20(3):224-226. |
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| Authors: | Yang Ying Lu Shiwei |
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| Abstract: | Selenium catalyzed reductive carbonylation of PhNO 2 in alcohol media was studied and a series of phenyl carbamate products were obtained. It was found that selenium has higher catalytic activity and the reaction gave higher yield and selectivity. A possible reaction scheme was postulated. |
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| Keywords: | selenium reductive carbonylation nitrobenzene alcohol phenyl carbamate |
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