Synthesis and X-ray structures of water-soluble tris(hydroxymethyl)phosphine complexes of rhodium(I) |
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| Authors: | Lorenzini Fabio Patrick Brian O James Brian R |
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| Institution: | Department of Chemistry, The University of British Columbia, Vancouver, B. C., Canada. |
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| Abstract: | The water-soluble Rh(I)-THP complexes: RhCl(1,5-cod)(THP) (), Rh(1,5-cod)(THP)(2)]Cl (), RhCl(THP)(4) (), and trans-RhCl(CO)(THP)(2) () have been synthesized and characterized, where THP = P(CH(2)OH)(3); - are the first potentially useful entries into Rh(I)-THP chemistry, while and are the first structurally characterized Rh(I)-THP complexes. |
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