Synthesis and structural characterization of two novel heterometallic clusters: [Rh4Pt2(CO)11(dppm)2] and [Ru2Rh2Pt2(CO)12(dppm)2 |
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Authors: | Koshevoy Igor O Grachova Elena V Tunik Sergey P Haukka Matti Pakkanen Tapani A Heaton Brian T Iggo Jonathan A Podkorytov Ivan S |
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Institution: | Department of Chemistry, St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, Staryi Peterhof 198504, Russian Federation. |
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Abstract: | Two novel heterometallic octahedral clusters Rh(4)Pt(2)(CO)(11)(dppm)(2)](1) and Ru(2)Rh(2)Pt(2)(CO)(12)(dppm)(2)](2) were synthesized by the reaction of Rh(2)Pt(2)(CO)(6)(dppm)(2)] with Rh(6)(CO)(14)(NCMe)(2)] and Ru(3)(CO)(12), respectively. Solid state structures of 1 and 2 have been established by a single crystal X-ray diffraction study. Two dppm ligands in 1 are bonded to one platinum and three rhodium atoms, which form an equatorial plane of the Rh(4)Pt(2) octahedron. Two rhodium and two platinum atoms bound to the diphosphine ligands in 2 are nonplanar to give an octahedral C2 symmetric Ru(2)Rh(2)Pt(2)(dppm)2 framework. The (31)P NMR investigation of and (1D, (31)P COSY, (31)P-(103)Rh] HMQC) and simulation of 1D spectral patterns showed that in both clusters the structures of the M(6)(PP)(2) fragments found in the solid state are maintained in solution. |
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