Mn(C2O4)(H2O)(0.25): an antiferromagnetic oxalato-based cage compound |
| |
| Authors: | Zhang Bin Zhang Yan Zhang Jinbiao Hao Xiang Zhu Daoben |
| |
| Institution: | BNLMS, Organic Solid Laboratory, CMS & Institute of Chemistry, Chinese Academy of Science, Beijing, 100190, P. R. China. zhangbin@iccas.ac.cn |
| |
| Abstract: | An oxalato-based cage compound Mn(C(2)O(4))(H(2)O)(0.25) was obtained using a solvothermal method. Mn is pentagonal bipyramidal coordinated with O from oxalato with three-atom and one-atom bridges. There are hydrogen bonds between the framework and clathrated H(2)O. A 3D long-range magnetic ordering was observed at 10.9 K. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
