Effects of poly(ethylene glycol) on the morphology and properties of biocomposites based on polylactide and cellulose nanofibers |
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| Authors: | Fatemeh Safdari Pierre J Carreau Marie C Heuzey Musa R Kamal |
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| Institution: | 1.Chemical Engineering Department, Research Center for High Performance Polymer and Composite Systems (CREPEC),Polytechnique Montreal,Montreal,Canada;2.Chemical Engineering Department, CREPEC,McGill University,Montreal,Canada |
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| Abstract: | Polylactide (PLA)/cellulose nanofiber (CNF) biocomposites were prepared via solution casting and direct melt mixing. To improve the compatibility, a masterbatch of CNFs and poly(ethylene glycol) (PEG) (1:2) was also prepared. The effects of PEG on the morphology and properties of the biocomposites were investigated. The dispersion/distribution of nanofibers in PLA was improved when the masterbatch was used and the composites were prepared in solution. Substantial effects on the rheological properties of solution-prepared PLA/CNF/PEG composites were observed compared to composites containing no PEG, whereas for melt-prepared composites no significant changes were detected. Increased crystalline content and crystallization temperature were observed for the composites prepared via the masterbatch and solvent casting. The storage modulus of PLA was increased by 42 and 553% at 25 and at 80 °C, respectively, for the solution-based PEG-compatibilized composite containing 2 wt% nanofibers. Also, a better light transmittance was measured for the PLA/CNF/PEG composites prepared in solution. |
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