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OH Radicals as Oxidizing Agent for the Abatement of Organic Pollutants in Gas Flows by Dielectric Barrier Discharges
Authors:Rudolph  R  Francke  K-P  Miessner  H
Institution:(1) Institut für Umwelttechnologien, Volmerstrasse 9B, D–, 12489 Berlin, Germany;(2) Dräger Safety, Volmerstrasse 7B, D–, 12489 Berlin, Germany
Abstract:OH radicals play an essential role in various plasma-chemical processes aimed at the abatement of organic and inorganic pollutants from off-air flows. We report about the oxidation of carbon monoxide in nonthermal air and nitrogen plasmas in dependence on CO inlet concentration and flow humidity. Thereby the reaction CO + OH rarr CO2 + H served as a diagnostic tool for OH radical determination in the dielectric barrier discharge at atmospheric pressure. The results were numerically fitted to the equations of a kinetic model allowing the determination of the average OH production efficiency (GOH-value) and OH lifetime (TOH) in dependence on flow humidity. Finally,results on ethyl acetate abatement obtained under similar experimental conditions were modeled by OH radical decomposition.
Keywords:VOC abatement  hydroxyl radicals  CO oxidation  nonthermal plasma
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