| 不对称酰胺基卟啉及其锌配合物的合成,表征及光谱研究 |
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| 引用本文： | 庄长福,王瑛,单宁,张加研,吴春华,师同顺.不对称酰胺基卟啉及其锌配合物的合成,表征及光谱研究[J].分子科学学报,2012(4):270-274. |
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| 作者姓名： | 庄长福 王瑛 单宁 张加研 吴春华 师同顺 |
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| 作者单位： | 西南林业大学材料工程学院;吉林大学化学学院 |
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| 基金项目： | 国家自然科学基金资助项目(31060099);云南省教育厅科学研究基金重点项目(2010Z040);云南省教育厅科学基金资助项目(2011Y268);西南林业大学重点学科建设项目(XKX200907) |
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| 摘 要： | 以CH2Cl2为溶剂,通过5-(4-氨基)苯基-10,15,20-三苯基卟啉(MATPP)与异烟酸直接反应得到一种不对称酰胺基卟啉配体(H2P),并合成了其锌配合物(ZnP),利用紫外-可见光谱、红外光谱、核磁共振氢谱、元素分析等测试方法对化合物的结构加以确认.同时,结合光谱法初步研究了卟啉的自聚合性质.研究表明,紫外-可见光谱显示了卟啉的J-聚合特征,荧光量子产率由于自聚合而降低.
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| 关 键 词： | 卟啉 配合物 合成 荧光光谱 |
Synthesize,characterization and spectroscopic property of an unsymmetrical imide porphyrin and its Zn compound |
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| ZHUANG Chang-fu,WANG Ying,SHAN Ning,ZHANG Jia-yan,WU Chun-hua,SHI Tong-shun.Synthesize,characterization and spectroscopic property of an unsymmetrical imide porphyrin and its Zn compound[J].Journal of Molecular Science,2012(4):270-274. |
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| Authors: | ZHUANG Chang-fu WANG Ying SHAN Ning ZHANG Jia-yan WU Chun-hua SHI Tong-shun |
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| Institution: | 1.Institute of Material Engineering,Southwest Forestry University,Kunming 650224,China; 2.College of chemistry,Jilin University,Changchun 130023,China) |
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| Abstract: | An unsymmetrical imide porphyrin ligand(H2P) has been synthesized by the reaction of the isonicotinic acid and 5-(4-aminophenyl)-10,15,20-triphenylporphyrin(MATPP) in CH2Cl2.The H2P and its compound ZnP were characterized by means of UV-Vis spectra,elemental analyses,IR spectra and 1H NMR spectra.The aggregating ability of porphyrins was explained primarily by spectroscopic properties.The results showed UV-Vis spectra exhibited the spectral feature of J-aggregated porphyrin and the fluorescence intensity was decreased with the aggregating of porphyrins. |
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| Keywords: | porphyrin compound synthesis fluorescence spectra |
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