| 罗丹明B合锌(Ⅱ)配合物的合成、分子结构与电性质研究 |
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| 引用本文： | 张岐,王流芳,林强,黄小荥.罗丹明B合锌(Ⅱ)配合物的合成、分子结构与电性质研究[J].分子科学学报,2000,16(4). |
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| 作者姓名： | 张岐 王流芳 林强 黄小荥 |
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| 基金项目： | 国家自然科学基金，海南省高校优秀中青年教师科研及教学奖励基金 |
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| 摘 要： | 合成了RB-Zn配合物，晶体结构分析结果表明配合物组成为晶体属单斜晶系、空间群为P21/n(#14)，晶胞参数为a研究了配合物的物质的量电导、IR和荧光光谱，同时对配体配合物的半导体行为进行了考察．
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| 关 键 词： | 罗丹明B 锌配合物 晶体结构 半导体行为 |
The synthesis, molecular structure and electric property of Rhodamine B complex with znic ( Ⅱ ) |
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| ZHANG Qi,WANG Liu-fang,LIN Qiang,Huang Xiao-ying.The synthesis, molecular structure and electric property of Rhodamine B complex with znic ( Ⅱ )[J].Journal of Molecular Science,2000,16(4). |
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| Authors: | ZHANG Qi WANG Liu-fang LIN Qiang Huang Xiao-ying |
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| Abstract: | The preparation and characterization of Zn(Ⅱ) complex with RB (Rhodamine Bwith dehydrogen－chloride), Zn(RB) (OAc)2 (H2O)] (A) , is described. Crystal of A ismonoclinic, P21/n with a =1.029 8(2) nm, b=1.890 1(4) nm, c=1.666 0(6) nm andβ= 105.24(3)° and have four formula units in the unit cell. The structure was determinedby standard methods and refined to R =0. 060, Rw=0. 068 on the basis of 5 755 independent reflections. The resultsuggests that coordination bond formed between the Zn atom andRB through the carboxylate group of the dye. The electrical conductivity of the complex andother related materials were also investigated. |
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| Keywords: | Rhodamine B Zn complex crystal structure semiconductor activity |
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