Synthesis of sedamine by tethered cyclofunctionalisation |
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Authors: | Bates Roderick W Boonsombat Jutatip |
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Institution: | Department of Chemistry, University of Exeter, Stocker Road, Exeter EX4 4QD, UK. R.W.Bates@exeter.ac.uk |
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Abstract: | The piperidine alkaloid, (+)-sedamine has been synthesised starting from (S)-1-phenyl-3-butenol using a stereoselective, intramolecular palladium-catalysed cyclocarbonylation reaction of a substituted hydroxylamine. |
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