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Virtually epimerization-free synthesis of peptide-alpha-thioesters
Authors:Hogenauer Tyrone J  Wang Qianli  Sanki Aditya K  Gammon Amy J  Chu Cherie H L  Kaneshiro Clyde M  Kajihara Yasuhiro  Michael Katja
Institution:Department of Chemistry, University of Texas at El Paso, El Paso, TX 79902, USA.
Abstract:Under slightly basic or neutral reaction conditions peptide-alpha-thioesters are photochemically synthesized from peptide-alpha-nitroindoline precursors, either in solution, or by direct photorelease from a solid support.
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