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化学探头法与荧光光谱法测定水中溶解氧量
引用本文:张 涛,刘金巍,蔡五田,曹月婷,赵 淼.化学探头法与荧光光谱法测定水中溶解氧量[J].中国无机分析化学,2015,5(1):28-30.
作者姓名:张 涛  刘金巍  蔡五田  曹月婷  赵 淼
作者单位:中国地质调查局 水文地质环境地质调查中心,河北 保定 071051;中国地质调查局 水文地质环境地质调查中心,河北 保定 071051;中国地质调查局 水文地质环境地质调查中心,河北 保定 071051;中国地质调查局 水文地质环境地质调查中心,河北 保定 071051;中国地质调查局 水文地质环境地质调查中心,河北 保定 071051
基金项目:中国地质调查局项目,典型水土污染区水文地质调查评价(1212011220985);青藏高原重点地区地下水水质调查评价(12120114059601)资助
摘    要:探讨了化学探头法和荧光光谱法测定水中溶解氧的关系。分别用F检验和t检验对两组数据进行了比较,结果表明两组数据的精密度和系统误差都没有显著差异,两种方法测定溶解氧的相对标准偏差(RSD,n=9)分别为0.35%,0.33%。进而又探讨了溶解氧与NaCl含量、温度之间的关系,结果表明溶解氧含量随NaCl含量的增加、温度的升高而逐渐降低。

关 键 词:化学探头法  荧光光谱法  溶解氧  显著性差异  F检验  t检验
收稿时间:9/7/2014 12:00:00 AM
修稿时间:2014/12/11 0:00:00

Determination of Dissolved Oxygen by Electrochemical Probe Method and Fluorescence Method
ZHANG Tao,LIU Jinwei,CAI Wutian,CAO Yueting and ZHAO Miao.Determination of Dissolved Oxygen by Electrochemical Probe Method and Fluorescence Method[J].Chinese Journal of Inorganic Analytical Chemistry,2015,5(1):28-30.
Authors:ZHANG Tao  LIU Jinwei  CAI Wutian  CAO Yueting and ZHAO Miao
Institution:Center for Hydrogeology and Environmental Geology,CGS,Baoding,Hebei 071051,China;Center for Hydrogeology and Environmental Geology,CGS,Baoding,Hebei 071051,China;Center for Hydrogeology and Environmental Geology,CGS,Baoding,Hebei 071051,China;Center for Hydrogeology and Environmental Geology,CGS,Baoding,Hebei 071051,China;Center for Hydrogeology and Environmental Geology,CGS,Baoding,Hebei 071051,China
Abstract:The relationship between the electrochemical probe method and the fluorescence method for the determination of dissolved oxygen in water was discussed. F-test and t-test were applied to compare the precision and systematic errors of the two methods by two groups of experimental data. The results showed that they were not significant differences. The relative standard deviations (RSDs, n=9) of the two methods were 0.35% and 0.33%, respectively. The relationship between dissolved oxygen and temperature, NaCl content were also discussed It is clear that the dissolved oxygen content increase with the increase of the content of NaCl and with the decrease of temperature .
Keywords:electrochemical probe method  fluorescence method  dissolved oxygen  significant difference  F-test  t-test
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