Cyclopentadienyl rhodium(III) complexes as catalysts for the insertion of phenyldiazoacetate into E−H bonds |
| |
| Institution: | 1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russian Federation;2. G. V. Plekhanov Russian University of Economics, 117997 Moscow, Russian Federation |
| |
| Abstract: | Rhodium(III) complexes catalyze the insertion of carbenoids generated from diazo compounds into E?H bonds (E = B, Si, N, but not C), although less efficiently than classical rhodium(II) carboxylates, despite formally higher oxidation state of the metal. |
| |
| Keywords: | rhodium complexes diazo compounds insertion catalysis cyclopentadienyl ligands |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
