One-pot assembling of selenazolines from elemental selenium,alkenes and acetonitrile |
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| Institution: | A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 664033 Irkutsk, Russian Federation |
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| Abstract: | A new method for assembling 1,3-selenazolines by the iodine- mediated reaction of the simplest building blocks such as elemental selenium, alkenes and acetonitrile has been discovered. A proposed mechanism includes the addition of the intermediate selenium iodides to alkene with subsequent solvent interception by the formed seleniranium ion. |
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| Keywords: | selenium organoselenium compounds alkenes acetonitrile iodine assistance solvent interception 1 3-selenazolines |
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