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Perfluorinated cyclo-tetrakis(phenylene sulfides): synthesis and structure
Institution:N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
Abstract:Perfluoro-cyclo-tetrakis(1,4-phenylene sulfide) has been synthesized by the reaction of tetrafluorobenzene-1,4-dithiol with perfluoro-1,4-bis(phenylthio)benzene. The reaction of tetrafluorobenzene-1,4-dithiol with perfluoro-m-xylene gives a macrocycle with 1,3- and 1,4-arrangement of bridged sulfur atoms.
Keywords:macrocycles  hexafluorobenzene  tetrafluorobenzene-1  4-dithiol  organofluorine compounds  organosulfur compounds  X-ray analyses
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