Near-IR absorbing donor–acceptor charge-transfer gallium complex,an example from non-transition metal chemistry |
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| Institution: | 1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603950 Nizhny Novgorod, Russian Federation;2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation |
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| Abstract: | Gallium(III) catecholates with bipyridine ligand (3,5-Cat)Ga(bipy)2]I and (3,6-Cat)GaI(bipy) (Cat is di-tert-butylcatecholate) were synthesized and characterized by single-crystal X-ray diffraction. The appearance of near-infrared ligand-to-ligand charge transfer for pentacoordinate complex was observed. |
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| Keywords: | gallium redox-active ligand catecholate diimine X-ray diffraction electronic spectroscopy |
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