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Copper(II) perchlorate complexes with antipyrine: synthesis,structure, cytotoxicity and DFT calculations
Institution:1. M. V. Lomonosov Institute of Fine Chemical Technologies, MIREA – Russian Technological University, 119571 Moscow, Russian Federation;2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation;3. Institute of Theoretical and Experimental Biophysics, Russian Academy of Sciences, 142290 Pushchino, Moscow Region, Russian Federation;4. Institute of Chemical Reagents and High Purity Chemical Substances, National Research Centre, ‘Kurchatov Institute’, 107076 Moscow, Russian Federation
Abstract:The synthesis, structure and properties of copper(II) perchlorate complexes with antipyrine (AP), Cu(AP)4(H2O)](ClO4)2 and Cu(AP)5](ClO4)2, are described and compared with those of alternative compounds containing different AP ligands.
Keywords:antipyrine  copper(II) perchlorate  crystal structure  cytotoxicity  reactive oxygen species
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