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ADSORPTION OF 2,4-DICHLOROBENZOXYACETIC ACID ONTO HYPERCROSSLINKED RESIN MODIFIED BY PHENOLIC HYDROXYL GROUP (AM-1)
Authors:Zheng-hao Fei  Jin-long Chen  ian-guo Cai  Yu-ping Qiu  Ai-min Li  Quan-xing Zhang
Institution:a.State Key Laboratory of Pollution Control and Resources Reuse; School of the Environment; Nanjing University; Nanjing 210093; China b.Institute of Applied Chemistry & Environmental Engineering; Department of Chemistry; Yancheng Teachers College; Jiangsu
Abstract: An experimental comparison of the adsorption properties of hypercrosslinked resin AM-1 modified by phenolic hydroxyl group with Amberlite XAD-4 toward 2,4-dichlorobenzoxyacetic acid was performed. This paper focuses on the static equilibrium adsorption behaviors and the adsorption thermodynamics. Two isotherm models were used to explain the results. It is seen that the Langmuir equation can give a perfect fit. The adsorption capacities from the different ranges of temperature, the adsorption enthalpy change value and the comparison of desorption conditions lead to the same conclusion that the adsorption of 2,4-dichlorobenzoxyacetic acid from water onto AM-1 is a type of physical and chemical transition.
Keywords:Hypercrosslinked polymeric adsorbent  4-Dichlorobenzoxyacetic acid  Thermodynamic properties  Chemical adsorption transition
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