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STUDIES OF ACTIVE DIACYLAMIDES OF BENZOTRIAZOLE Ⅰ. SYNTHESIS OF POLYAMIDES AND POLYESTERS*
引用本文:陆承勋,李强.STUDIES OF ACTIVE DIACYLAMIDES OF BENZOTRIAZOLE Ⅰ. SYNTHESIS OF POLYAMIDES AND POLYESTERS*[J].高分子科学,1985,0(1):42-47.
作者姓名:陆承勋  李强
作者单位:Department of Chemistry,Peking University,Beijing,Department of Chemistry,Peking University,Beijing
摘    要:Two new routes to polyamides and polyesters were established, based on the polycondensationof new typical active diacylamide of benzotriazole, such as 1, 1'-(isophthaloyl) bisbenzotriazole(IPBBT) and 1, 1'-(terephthaloyl)bisbenzotriazole (PBBT) with diamines, diols and diphenol underdifferent mild conditions. The N-acylation of polycondensation occurred at room temperaturewithout added catalyst, the O-acylation of polycondensation had to complete in the presence oftriethylamine as a catalyst at 60℃.

收稿时间:1984-07-28

STUDIES OF ACTIVE DIACYLAMIDES OF BENZOTRIAZOLE Ⅰ. SYNTHESIS OF POLYAMIDES AND POLYESTERS*
LU Chengxun,LI Qiang.STUDIES OF ACTIVE DIACYLAMIDES OF BENZOTRIAZOLE Ⅰ. SYNTHESIS OF POLYAMIDES AND POLYESTERS*[J].Chinese Journal of Polymer Science,1985,0(1):42-47.
Authors:LU Chengxun  LI Qiang
Institution:Department of Chemistry. Peking University; Beijing
Abstract: Two new routes to polyamides and polyesters were established, based on the polycondensationof new typical active diacylamide of benzotriazole, such as 1, 1'-(isophthaloyl) bisbenzotriazole(IPBBT) and 1, 1'-(terephthaloyl)bisbenzotriazole (PBBT) with diamines, diols and diphenol underdifferent mild conditions. The N-acylation of polycondensation occurred at room temperaturewithout added catalyst, the O-acylation of polycondensation had to complete in the presence oftriethylamine as a catalyst at 60℃.
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