| THE POLYMERIZATION OF ACETYLENE BY COORDINATION CATALYSTS COMPOSED OF NEODYMIUM COMPOUND, ALUMINUM TRIALKYL AND A THIRD COMPONENT |
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| 作者姓名： | 张一峰 蔡一平 杨慕杰 沈之荃 |
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| 作者单位： | Department of Chemistry，Zhejiang University，Hangzhou，Department of Chemistry，Zhejiang University，Hangzhou，Department of Chemistry，Zhejiang University，Hangzhou，Department of Chemistry，Zhejiang University，Hangzhou |
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| 摘 要： | This paper describes the polymerization of acetylene by coordination catalysts composed ofvarious neodymium compounds, (Nd (P_(204))_3; Nd (P_(507))_3; Nd (NO_3)_3 3P_(350); Nd (BA)_3.2H_2O; andNd (acac)_3.2H_2O), aluminum trialkyl and an electron donor. The catalysts show fairly high catalyticactivity and high cis stereospecificity on acetylene polymerization at 30℃.
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| 收稿时间： | 1985-07-28 |
THE POLYMERIZATION OF ACETYLENE BY COORDINATION CATALYSTS COMPOSED OF NEODYMIUM COMPOUND, ALUMINUM TRIALKYL AND A THIRD COMPONENT* |
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| ZHANG Yifeng,CAI Yiping,YANG Mujie,SHEN Zhiquan.THE POLYMERIZATION OF ACETYLENE BY COORDINATION CATALYSTS COMPOSED OF NEODYMIUM COMPOUND, ALUMINUM TRIALKYL AND A THIRD COMPONENT[J].Chinese Journal of Polymer Science,1985,0(4):367-372. |
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| Authors: | ZHANG Yifeng CAI Yiping YANG Mujie SHEN Zhiquan |
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| Institution: | Department of Chemistry; Zhejiang University; Hangzhou |
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| Abstract: | This paper describes the polymerization of acetylene by coordination catalysts composed ofvarious neodymium compounds, (Nd (P204)3; Nd (P507)3; Nd (NO3)3 3P350; Nd (BA)3.2H2O; and Nd (acac)3.2H2O), aluminum trialkyl and an electron donor. The catalysts show fairly high catalyticactivity and high cis stereospecificity on acetylene polymerization at 30℃. |
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