| STUDY OF HETEROCYCLIC POLYMER COMPLEXES Ⅰ. POLYPHENYLQUINOXALINE-PLATINUM AND RHODIUM COMPLEXES* |
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| 引用本文： | 卢凤才,王玉兰,王殿勋,余阳.STUDY OF HETEROCYCLIC POLYMER COMPLEXES Ⅰ. POLYPHENYLQUINOXALINE-PLATINUM AND RHODIUM COMPLEXES*[J].高分子科学,1985,0(1):82-84. |
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| 作者姓名： | 卢凤才 王玉兰 王殿勋 余阳 |
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| 作者单位： | Institute of Chemistry，Academia Sinica，Beijing，Institute of Chemistry，Academia Sinica，Beijing，Institute of Chemistry，Academia Sinica，Beijing，Beijing Research Institute for Nutritional Resources |
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| 摘 要： | Two new polyphenylquinoxaline-platinum and rhodium complexes were synthesized and iden-tified by X-ray photoelectron spectroscopy. Their catalytic properties on hydrosilylation and hy-drogenation of olefines have been investigated. It was found that these polymer complexes possessedhigh selective catalytic activities, and were easily recoverable after each reaction and could berepeatedly used for more than 10 times while maintaining the same effectiveness.
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| 收稿时间： | 1984-01-03 |
STUDY OF HETEROCYCLIC POLYMER COMPLEXES Ⅰ. POLYPHENYLQUINOXALINE-PLATINUM AND RHODIUM COMPLEXES* |
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| LU Fengcai,WANG Yulan,WANG Dianxun,YU Yang.STUDY OF HETEROCYCLIC POLYMER COMPLEXES Ⅰ. POLYPHENYLQUINOXALINE-PLATINUM AND RHODIUM COMPLEXES*[J].Chinese Journal of Polymer Science,1985,0(1):82-84. |
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| Authors: | LU Fengcai WANG Yulan WANG Dianxun YU Yang |
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| Institution: | Institute of Chemistry; Academia Sinica; Beijing |
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| Abstract: | Two new polyphenylquinoxaline-platinum and rhodium complexes were synthesized and iden-tified by X-ray photoelectron spectroscopy. Their catalytic properties on hydrosilylation and hy-drogenation of olefines have been investigated. It was found that these polymer complexes possessedhigh selective catalytic activities, and were easily recoverable after each reaction and could berepeatedly used for more than 10 times while maintaining the same effectiveness. |
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