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SYNTHESIS AND PROPERTIES OF POLYSTYRENE/LAPONITE NANOCOMPOSITES
引用本文:侯万国 Wei-anzhao Dong-xiangLi.SYNTHESIS AND PROPERTIES OF POLYSTYRENE/LAPONITE NANOCOMPOSITES[J].高分子科学,2004,0(5):459-462.
作者姓名:侯万国  Wei-anzhao  Dong-xiangLi
作者单位:KeyLabforColloidandInterfaceChemistryofMinistryofEducation,ShandongUniversity,Jinan250100,China
摘    要:Exfoliated polystyrene (PS)/laponite nanocomposites were prepared successfully. The characteristic doo1 diffraction peak of organo-laponite disappeared in the XRD patterns of nanocomposites, indicating that the laponite layers were exfoliated and the ordered crystal structure of laponite was destroyed because of the styrene polymerization. TEM observations showed that the exfoliated laponite primary particles were dispersed randomly in the PS matrix with lateral dimensions from 1 nm to 10 rim. SEM results showed that the PS/laponite nanocomposite particles were almost monodispersed spheres with the size of about 120 rim. Because of the interaction between PS and laponite nanolayers, the nanocomposites exhibited higher thermal stability and glass transition temperature when compared to pure PS.

关 键 词:合成  聚苯乙烯  合成锂皂石  粘土  纳米复合物  X射线衍射  扫描电子显微镜  结构  形态学  热性质
收稿时间:2003-05-21
修稿时间:2003-10-20

SYNTHESIS AND PROPERTIES OF POLYSTYRENE/LAPONITE NANOCOMPOSITES
Wan-guo Hou,Wei-an Zhao,Dong-xiang Li.SYNTHESIS AND PROPERTIES OF POLYSTYRENE/LAPONITE NANOCOMPOSITES[J].Chinese Journal of Polymer Science,2004,0(5):459-462.
Authors:Wan-guo Hou  Wei-an Zhao  Dong-xiang Li
Institution:Key Lab for Colloid and Interface Chemistry of Ministry of Education; Shandong University; Jinan 250100; China
Abstract:Exfoliated polystyrene (PS)/laponite nanocomposites were prepared successfully. The characteristic d001diffraction peak of organo-laponite disappeared in the XRD patterns of nanocomposites, indicating that the laponite layers were exfoliated and the ordered crystal structure of laponite was destroyed because of the styrene polymerization. TEM observations showed that the exfoliated laponite primary particles were dispersed randomly in the PS matrix with lateral dimensions from 1 nm to 10 nm. SEM results showed that the PS/laponite nanocomposite particles were almost monodispersed spheres with the size of about 120 nm. Because of the interaction between PS and laponite nanolayers, the nanocomposites exhibited higher thermal stability and glass transition temperature when compared to pure PS.
Keywords:Polystyrene (PS)  Laponite  Nanocomposites  POLYSTYRENE  PROPERTIES  SYNTHESIS  NANOCOMPOSITES  thermal stability  glass transition temperature  pure  interaction  nanocomposite particles  monodispersed  size  results  observations  primary  matrix  lateral  dimensions  layers  ordered  crystal structure
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