| NETWORK CROWN ETHER POLYMERS WITH CENTRIC FUNCTIONAL GROUP (Ⅳ) SYNTHESIS OF NETWORK CROWN ETHER POLYMER WITH PENDANT DIETHYLAMINO THIAALKYL GROUP AND ITS PLATINUM COMPLEX* |
| |
| 引用本文： | 陈远荫,孟令芝,殷以华,耿成爱.NETWORK CROWN ETHER POLYMERS WITH CENTRIC FUNCTIONAL GROUP (Ⅳ) SYNTHESIS OF NETWORK CROWN ETHER POLYMER WITH PENDANT DIETHYLAMINO THIAALKYL GROUP AND ITS PLATINUM COMPLEX*[J].高分子科学,1994,0(4):316-322. |
| |
| 作者姓名： | 陈远荫 孟令芝 殷以华 耿成爱 |
| |
| 作者单位： | Department of Chemistry，Wuhan University，Wuhan 430072，Department of Chemistry，Wuhan University，Wuhan 430072，Department of Chemistry，Wuhan University，Wuhan 430072，The Second Middle School in Caidian，Wuhan 430100 |
| |
| 基金项目： | This work was supported by the National Natural Science Foundation of China |
| |
| 摘 要： | The title polymer was prepared from 5-diethylamino-3-thia-pentyl glycidyl ether anddiethylene glycol bisglycidyl ether via ring-opening copolymerization. It was found that thisreaction could be catalyzed by sodium, but not Lewis acid. The obtained polymer can coordinatewith platinum compound, and the platinum complex is a new kind of catalyst for thehydrosilylation of olefins with triethoxysilane.
|
| 收稿时间： | 1993-12-09 |
NETWORK CROWN ETHER POLYMERS WITH CENTRIC FUNCTIONAL GROUP (Ⅳ) SYNTHESIS OF NETWORK CROWN ETHER POLYMER WITH PENDANT DIETHYLAMINO THIAALKYL GROUP AND ITS PLATINUM COMPLEX* |
| |
| CHEN Yuanyin,MENG Lingzhi,YIN Yihua,GENG Chengai.NETWORK CROWN ETHER POLYMERS WITH CENTRIC FUNCTIONAL GROUP (Ⅳ) SYNTHESIS OF NETWORK CROWN ETHER POLYMER WITH PENDANT DIETHYLAMINO THIAALKYL GROUP AND ITS PLATINUM COMPLEX*[J].Chinese Journal of Polymer Science,1994,0(4):316-322. |
| |
| Authors: | CHEN Yuanyin MENG Lingzhi YIN Yihua GENG Chengai |
| |
| Institution: | Department of Chemistry; Wuhan University; Wuhan; The Second Middle School in Caidian |
| |
| Abstract: | The title polymer was prepared from 5-diethylamino-3-thia-pentyl glycidyl ether anddiethylene glycol bisglycidyl ether via ring-opening copolymerization. It was found that thisreaction could be catalyzed by sodium, but not Lewis acid. The obtained polymer can coordinatewith platinum compound, and the platinum complex is a new kind of catalyst for thehydrosilylation of olefins with triethoxysilane. |
| |
| Keywords: | Crown ether Crown ether polymer Platinum complex Hydrosilylation catalyst |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《高分子科学》浏览原始摘要信息 |
| 点击此处可从《高分子科学》下载免费的PDF全文 |
