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Mechanism of fracture in glassy polymers. III. Direct observation of the craze ahead of the propagating crack in poly(methyl methacrylate) and polystyrene
Authors:Roger P Kambour
Abstract:Observation of optical interference fringes at the tip of a crack in a glassy polymer allows the construction of the configurations of the crack tip and the craze that precedes it. The craze extends 25 μ beyond the crack tip in poly(methyl methacrylate) and 550 μ beyond the tip in the polystyrene studied. The craze at the crack tip in PMMA may be seen to deform elastically as much as 100% under stress before crack propagation recommences. Such deformation is estimated to account for as much as 40% of the nominal Griffith energy of crack propagation.
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