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Reduction of Sulphur-containing Aromatic Nitro Compounds with Hydrazine Hydrate over Iron(Ⅲ) Oxide-MgO Catalyst
作者姓名:Qi  Xun  SHI  Rong  Wen  LU  Zhu  Xia  ZHANG  De  Feng  ZHAO
作者单位:State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012
摘    要:Sulphur-containing aromatic amines were prepared efficiently in good to excellent yields by reduction of the corresponding sulphur-containing aromatic nitro compounds with hydrazine hydrate in the presence of iron(Ⅲ) oxide-MgO catalyst. The catalyst exhibited high activity and stability for the reduction of sulphur-containing aromatic nitro compounds. The yields of sulphur-containing aromatic amines were up to 91-99 % at 355 K after reduction for 1-4 h over this catalyst.

关 键 词:铁(Ⅲ)氧化物-氧化镁催化剂  水合肼  含硫芳香族硝基化合物  还原反应
收稿时间:2005-08-25
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