An efficient,recoverable fluorous organocatalyst for accelerating the DABCO-promoted Morita-Baylis-Hillman reaction |
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| Authors: | Yi Bo Huanga b Wen Bin Yia Chun Caia a |
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| Institution: | a School of Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094, China;b Department of Pharmacy, Changzhou Institute of Engineering Technology, Changzhou 213164, China |
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| Abstract: | A convenient method for Morita-Baylis-Hillman reaction of arylaldehydes with methyl acrylate has been developed by using fluorous-tag organocatalyst 1-4-(perfluorooctyl)phenyl]-3-phenylthiourea and DABCO at room temperature.The fiuorous, organocatalyst could be recovered from the reaction mixture by fiuorous solid-phase extraction(F-SPE) with excellent purity for direct reuse. |
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| Keywords: | Organocatalyst Morita-Baylis-Hillman reaction Fluorous solid phase extraction(F-SPE) |
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