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Chiroptical coassemblies between organic carboxylic acids and amino acid derivatives with C3-symmetry
Institution:1. Key Laboratory of Thermo-Fluid Science and Engineering of Ministry of Education, School of Energy and Power Engineering, Frontier Institute of Science and Technology, Xi''an Jiaotong University, Xi''an 710054, China;2. School of Chemistry, Xi''an Key Laboratory of Sustainable Energy Materials Chemistry, Xi''an Jiaotong University, Xi''an 710049, China;3. School of Materials Science and Engineering, Xi''an Jiaotong University, Xi''an 710049, China;1. Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, School of Energy and Environment, Southeast University, Nanjing 210096, China;2. Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;3. School of Energy Science and Engineering, Central South University, Changsha 410083, China;1. School of Chemistry and Chemical Engineering, Shihezi University/State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi 832000, China;2. State Key Laboratory of Supramolecular Structure and Materials, Institute of Theoretical Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
Abstract:Benzimidazole amino acid derivatives behave as supramolecular hosts to include organic acids via complementary hydrogen bonding whereby supramolecular chirality and chiroptical properties could be manipulated. Organic acids enhanced the chiral assembly that showed tunable circularly polarized luminescence with high dissymmetry g-factors at 10−2 grade.
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